Thermal Expansion

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Thermal Expansion


31.1 Introduction


When solid materials are heated, most expand (although some very flexible rubbers actually contract). This expansion is defined by the linear coefficient of thermal expansion, α. If a rod-shaped specimen (having initial and final lengths L0 and L) is heated through a temperature interval ΔT, then


LL0=L0αΔT



This equation can be rewritten as.


ɛ=LL0L0=αΔT



where ɛ is the (linear) thermal strain.


For an isotropic material, the volume strain is given by


Δ=ΔVV=3ɛ=3αΔT



We have already come across thermal expansion in several places: Section 17.4 (thermal cracking of PUR foam insulation panels); Chapter 18, Worked Example 1 (thermal fatigue of copper water-cooling plates); Example 18.7 (thermal fatigue in a boiler); Section 19.5 (residual stresses in welds); Example 29.11 (shrink fitting of compressor wheels). α is an important material property, with a huge range of applications—and consequences.


Worked Example 1


In Section 17.4, we said that the thermal stress σ in the PUR foam was


σ=αΔTE1υ



where E is Young’s modulus and υ is Poisson’s ratio. But how do we prove this?


We saw in Example 7.11 that the elastic stress-strain relations for an isotropic material are


ɛ1=σ1Eυσ2Eυσ3Eɛ2=σ2Eυσ1Eυσ3Eɛ3=σ3Eυσ1Eυσ2E



We can easily modify these relations to include the effect of thermal expansion by simply adding the thermal strain to each strain component, giving


ɛ1=σ1Eυσ2Eυσ3E+αΔTɛ2=σ2Eυσ1Eυσ3E+αΔTɛ3=σ3Eυσ1Eυσ2E+αΔT



Now let’s look at the free surface of the foam (see Figure 17.7). We locate principal axes 1p and 2p in the plane of the surface, and 3p perpendicular to the surface. σ3 = 0 (a free surface cannot support a stress) and ɛ1 = ɛ2 = 0 (the surface cannot contract sideways, because it is fixed to the steel plate). So


0=σ1Eυσ2E+αΔT0=σ2Eυσ1E+αΔTɛ3=υσ1Eυσ2E+αΔT



This gives σ1 = σ2 = σ (equibiaxial), 0=σEυσE+αΔTsi8_e, and σ=αΔTE1υsi9_e.


(Note that ΔT is negative, because the free surface of the foam has been cooled. So σ is a tensile stress.)■


How do we measure α? As a rough approximation for many metals and ceramics, a temperature rise of 100°C produces a thermal strain of one in a thousand (equivalent to 1 thou per inch). Measuring α for these materials therefore requires very accurate measurement of length and precise control of temperature. This presents considerable challenges, especially when measurements have to be done at high temperatures. If traditional mechanical methods (e.g., micrometers, displacement transducers) are used, great care must be taken that the measuring equipment itself does not expand (or if it does, this is calibrated out). Most of these problems have now been solved using noncontact methods, such as laser interferometry (which is also extremely accurate).


31.2 Coefficients of Thermal Expansion


Data for α are shown in Table 31.1. Within each materials class the values vary a lot, although the range of values for metals and ceramics is much the same. What is notable, however, are the large values for polymers (and some polymer-based composites)—typically 5 or 10 times those for metals and ceramics. α itself is a weak function of temperature—the values shown in the table are average values over a finite temperature range (often 25–125°C). For exacting applications, data must be obtained over the relevant temperature range, which may be hundreds of degrees higher.



Table 31.1











































































































































































Data for Linear Coefficient of Thermal Expansion, α (for Example, a Value of “6” in the Table Means 6 × 10− 6 K− 1)
Material α
Metals
Zinc 31
Zinc die-casting alloy 27
Magnesium 26
Aluminum 22.5
Aluminum alloys 20–24
Copper 17
Copper alloys 18–20
Iron, carbon steel, low-alloy steel 12
High-alloy steels 10–18
Stainless steels 17
Nickel 13
Superalloys 12
Titanium 9
Ti-6Al4V 8
Controlled-expansion alloys
    Kovar (Nilo-K), 54Fe29Ni17Co 6
    Invar, 64Fe36Ni 1.3
    Ultra-pure Invar (< 0.001Co) 0.6
Ceramics and glasses
Cement and (unreinforced) concrete 10–14
Soda glass 8.5
Alumina 8.5
Zirconia 8
Limestone 8
Granite 8
Silicon carbide 4.3
Borosilicate glass 4
Silicon nitride 3.2
Porcelain 3
Diamond 1.2
Polymers (thermoplastics)
Polypropylene (PP) 170
Polyethylene, high density (HDPE) 140
PTFE 130
Nylons 110–120
Polyurethane (PU) 80
Polystyrene (PS) 70–100
Polycarbonate (PC) 70
PMMA (Perspex) 55–70
Polyvinylchloride, unplasticized (UPVC) 50–70
Polyetheretherketone (PEEK) 50
Polymers (thermosets/resins)
Epoxies 55–90
Polyesters 50–100
Phenol formaldehyde 26–60
Polymers (rubbers/elastomers)
Silicone 250–300
Fluorosilicone 200
Nitrile butadiene (NBR) 200
Fluorocarbon (Viton) 200
Polychlorotrifluoroethylene (PCTFE) 150
Polyisoprene, polybutadiene, polychloroprene ≈ 600
Polymer-matrix composites
Glass-filled nylons 50–60
Tufnol (paper or woven cloth laminated phenolic resin) 18–22

Aug 9, 2021 | Posted by in General Engineer | Comments Off on Thermal Expansion
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